More specifically, the present invention is directed to processes for the preparation of toner compositions, which comprise (i) preparing an ionic pigment mixture by dispersing a colorant, especially pigment, such as carbon black, HOSTAPERM PINK???, or PV FAST BLUE???, in an aqueous surfactant solution containing a cationic surfactant, such as dialkylbenzene dialkylammonium chloride like SANIZOL B