| http://www.w3.org/ns/prov#value | - A method of synthesizing a metal nitrosyl, comprising: a) deprotonating a ligand in a solvent to produce a deprotonated ligand, wherein said ligand is a pentadentate or tetradentate ligand having one or more carboxamido groups; b) reacting a metal salt with said deprotonated ligand to produce a solution comprising an intermediate, wherein said metal is group 7 or group 8 transition metal in a +2,
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